About
Gold
Gold is a chemical element with the symbol Au (from the Latin
aurum) and atomic number 79. It is a highly sought-after precious
metal which, for many centuries, has been used as money, a
store of value and in jewelery. The metal occurs as nuggets
or grains in rocks, underground "veins" and in alluvial
deposits. It is one of the coinage metals. It is a dense,
soft, shiny, yellow metal, and is the most malleable and ductile
of the known metals.
Gold
forms the basis for a monetary standard used by the International
Monetary Fund (IMF) and the Bank for International Settlements
(BIS). Its ISO currency code is XAU. Modern industrial uses
include dentistry and electronics, where gold has traditionally
found use because of its good resistance to oxidative corrosion.
Chemically,
gold is a trivalent and univalent transition metal. Gold does
not react with most chemicals, but is attacked by chlorine,
fluorine, aqua regia and cyanide. Gold dissolves in mercury,
forming amalgam alloys. In particular, gold is insoluble in
nitric acid, which will dissolve most other metals. Nitric
acid has long been used to confirm the presence of gold in
items, and this is the origin of the colloquial term "acid
test," referring to a gold standard test for genuine
value.
Gold is a metallic element with a characteristic yellow color,
but can also be black or ruby when finely divided, while colloidal
solutions are intensely colored and often purple. These colors
are the result of gold's plasmon frequency lying in the visible
range, which causes red and green light to be reflected, and
blue light to be absorbed. Only silver colloids exhibit the
same interactions with light, albeit at a shorter frequency,
making silver colloids yellow in color.
Gold
is the most malleable and ductile metal; a single gram can
be beaten into a sheet of one square meter, or an ounce into
300 square feet. Gold readily forms alloys with many other
metals. These alloys can be produced to increase the hardness
or to create exotic colors. Adding copper yields a redder
metal, iron blue, aluminium purple, platinum metals white,
and natural bismuth together with silver alloys produce black.
Native gold contains usually eight to ten percent silver,
but often much more — alloys with a silver content over
20% are called electrum. As the amount of silver increases,
the color becomes whiter and the specific gravity becomes
lower.
Gold
is a good conductor of heat and electricity, and is not affected
by air and most reagents. Heat, moisture, oxygen, and most
corrosive agents have very little chemical effect on gold,
making it well-suited for use in coins and jewelry; conversely,
halogens will chemically alter gold, and aqua regia dissolves
it by virtue of the elemental chlorine generated by this acid
mixture.
Common
oxidation states of gold include +1 (gold(I) or aurous compounds)
and +3 (gold(III) or auric compounds). Gold ions in solution
are readily reduced and precipitated out as gold metal by
adding any other metal as the reducing agent. The added metal
is oxidized and dissolves allowing the gold to be displaced
from solution and be recovered as a solid precipitate.
Recent
research undertaken by Sir Frank Reith of the Australian National
University shows that microbes play an important role in forming
gold deposits, transporting and precipitating gold to form
grains and nuggets that collect in alluvial deposits. [1]
The
concentration of free electrons in gold metal is 5.90×1022
cm-3.
High
quality pure gold is tasteless.
Pure gold is too soft for ordinary use and is typically hardened
by alloying with silver, copper, or other metals. In various
countries, gold, and its many alloys, are most often used
in jewelry, coinage and as a standard for monetary exchange.
When sold in the form of jewelry, gold is measured in carats
(k), with pure gold being designated as 24k. It is, however,
more commonly sold in lower measurements of 22k, 18k, 14k
and 10k. A lower "k" indicates that a higher percent
of copper or silver in the alloy, with copper being the more
commonly used metal. Fourteen carat gold-copper alloy is nearly
identical in color to certain bronze alloys, and both may
be used to produce police and other badges. Eighteen carat
gold, with a high copper content, is found in some antique
jewelry and has a distinct, though not dominant, copper cast,
creating an attractively warm color. A similar carat weight,
when alloyed with silvery metals, appears less warm in color.
Some low carat white metal alloys are sold as "white
gold" and are silver in appearance, but have a sightly
more yellow cast. They are far more resistant to corrosion
than are either pure silver or sterling silver.
Carat
weights of twenty and higher are more common in modern jewelry.
Gold coins intended for circulation prior to the 1930's were
typically 22k, for hardness. Modern collector/investment bullion
coins (which do not require good mechanical wear properties)
are typically 24k, although the American Gold Eagle continues
to be made at 22k. Currently, the Canadian Gold Maple Leaf
coin contains the highest purity gold of any popular bullion
coin, at 99.99% (.9999 fine). Because of its high electrical
conductivity and resistance to corrosion and other desirable
combinations of physical and chemical properties, gold has
emerged in the late 20th century as an essential industrial
metal, particularly when used as a thin plating on printed
circuit board contacts and electrical connectors.
History
of Gold
Gold has been known and highly valued since prehistoric times.
It may have been the first metal used by humans and was valued
for ornamentation and rituals. Egyptian hieroglyphs from as
early as 2600 BC describe gold, which king Tushratta of the
Mitanni claimed was "more plentiful than dirt" in
Egypt. Egypt and Nubia had the resources to make them major
gold-producing areas for much of history. Gold is also mentioned
several times in the Old Testament, and is included with the
gifts of the magi in the first chapters of Matthew New Testament
The south-east corner of the Black Sea was famed for its gold.
Exploitation is said to date from the time of Midas, and this
gold was important in the establishment of what is probably
the world's earliest coinage in Lydia between 643 and 630
BC.
The
European exploration of the Americas was fueled in no small
part by reports of the gold ornaments displayed in great profusion
by Native American peoples, especially in Central America,
Peru, and Colombia.
Gold
has long been considered one of the most precious metals,
and its value has been used as the standard for many currencies
(known as the gold standard) in history. Gold has been used
as a symbol for purity, value, royalty, and particularly roles
that combine these properties. Gold as a sign of wealth and
prestige was made fun of by Thomas More in his treatise Utopia.
On that imaginary island, gold is so abundant that it is used
to make chains for slaves, tableware and lavatory-seats. When
ambassadors from other countries arrive, dressed in ostentatious
gold jewels and badges, the Utopians mistake them for menial
servants, paying homage instead to the most modestly-dressed
of their party.
There
is an age-old tradition of biting gold in order to test its
authenticity. Although this is certainly not a professional
way of examining gold, the bite test should score the gold
because gold is considered a soft metal according to the Mohs'
scale of mineral hardness. The purer the gold the easier it
should be to mark it. Painted lead can cheat this test because
lead is softer than gold (and may invite a small risk of lead
poisoning if sufficient lead is absorbed by the biting).
This 156 ounce nugget was found by an individual prospector
in the Southern California Desert using a metal detector.Gold
in antiquity was relatively easy to obtain geologically; however,
75% of all gold ever produced has been extracted since 1910.[5]
It has been estimated that all the gold in the world that
has ever been refined would form a single cube 20 m (66 ft)
on a side (8000 m³).
The
primary goal of the alchemists was to produce gold from other
substances, such as lead — presumably by the interaction
with a mythical substance called the philosopher's stone.
Although they never succeeded in this attempt, the alchemists
promoted an interest in what can be done with substances,
and this laid a foundation for today's chemistry. Their symbol
for gold was the circle with a point at its center, which
was also the astrological symbol, the Egyptian hieroglyph
and the ancient Chinese character for the Sun. For modern
attempts to produce artificial gold, see gold synthesis.
During
the 19th century, gold rushes occurred whenever large gold
deposits were discovered. The first major gold strike in the
United States occurred in a small north Georgia town called
Dahlonega.[6] Further gold rushes occurred in California,
Colorado, Otago, Australia, Witwatersrand, Black Hills, and
Klondike.
Because
of its historically high value, much of the gold mined throughout
history is still in circulation in one form or another

Gold
Production
Economic gold extraction can be achieved from ore grades as
little as 0.5 g/1000 kg (0.5 ppm) on average in large easily
mined deposits. Typical ore grades in open-pit mines are 1–5
g/1000 kg (1-5 ppm), ore grades in underground or hard rock
mines are usually at least 3 g/1000 kg (3 ppm) on average.
Since ore grades of 30 g/1000 kg (30 ppm) are usually needed
before gold is visible to the naked eye, in most gold mines
the gold is invisible.
Since
the 1880s, South Africa has been the source for a large proportion
of the world’s gold supply. Production in 1970 accounted
for 79% of the world supply, producing about 1,000 tonnes.
However, production in 2004 was 342 tonnes. This decline was
due to the increasing difficulty of extraction and changing
economic factors affecting the industry in South Africa.
The
city of Johannesburg was built atop the world's greatest gold
finds. Gold fields in the Free State and Gauteng provinces
are deep and require the world's deepest mines. The Second
Boer War of 1899–1901 between the British Empire and
the Afrikaner Boers was at least partly over the rights of
miners and possession of the gold wealth in South Africa.
Other major producers are Canada, United States and Australia.
Mines in South Dakota and Nevada supply two-thirds of gold
used in the United States. Siberian regions of Russia also
used to be significant in the global gold mining industry.
Kolar Gold Fields in India is another example of a city being
built on the greatest gold deposits in India. In South America,
the controversial project Pascua Lama aims at exploitation
of rich fields in the high mountains of Atacama Desert, at
the border between Chile and Argentina. Today about one-quarter
of the world gold output is estimated to originate from artisanal
or small scale mining.
After
initial production, gold is often subsequently refined industrially
by the Wohlwill process or the Miller process. Other methods
of assaying and purifying smaller amounts of gold include
parting and inquartation as well as cuppelation, or refining
methods based on the dissolution of gold in aqua regia.
The
world's oceans hold a vast amount of gold, but in very low
concentrations (perhaps 1-2 parts per billion). Fritz Haber
(the German inventor of the Haber process) attempted commercial
extraction of gold from sea water in an effort to help pay
Germany's reparations following the First World War. Unfortunately,
his assessment of the concentration of gold in sea water was
unduly high, probably due to sample contamination. The effort
produced little gold and cost the German government far more
than the commercial value of the gold recovered. No commercially
viable mechanism for performing gold extraction from sea water
has yet been identified. Gold synthesis is not economically
viable and is unlikely to become so in the foreseeable future.
The
average gold mining and extraction costs are $238 per troy
ounce but these can vary widely depending on mining type and
ore quality.
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